Future Energy: Nano Diamond Battery Solutions

Nuclear Voltaic Power-source
The diamond-based charge generator comprises radioisotopes embedded in diamond, Radioisotopes can decay and release an alpha particle, beta particle, or neutron which can be the power source.
The first diamond layer comprises a P+ -type diamond and the second layer comprises a P-type diamond. At least one diamond-based charge generator comprises an ohmic contact layer and a Schottky contact layer. The ohmic contact layer comprises Ti, Zr, Hf, TiC, ZrC, HfC, Zr—Ti—C, Hf—Ti—C, Zr—Hf—C, Ti—Hf—C, or Ti—Zr—Hf—C and the Schottky contact layer comprises Al, Ti, Ni, Au, Ag, Nb, Cu, Cr, and Pt.
Solution
- The solution relates to diamond-based charge generator to improve the power output of the nano diamond battery.
- The benefit of using diamond is that the wide bandgap (5.5 eV) can allow for a high voltage (typically up to 2 V), a long carrier lifetime (typically 2000 ns) which can allow it to have a near 100% charge collection efficiency, and an extremely high radiation hardness that allows the device to be used over a significantly long period to time.
- Diamond-based charge generator comprises a first diamond layer and a second diamond layer.
- Radioisotopes of shorter half-life but of higher radioactivity can be used to increase the power output.
- Diamond nuclear voltaic can power applications for as long as the radioisotopes last.
Application
- The application of nuclear diamond battery such as smartphones (3.7 V), electric vehicle (4.2 V), Internet of Things (IoT, <1.5 V).
- Nuclear Diamond batteries can also be used in pacemakers and hearing aids.
Comment
- The method is suitable for enhancing the efficiency of nano diamond battery.
- Radioisotopes of shorter half-life but of higher radioactivity can be used to increase the power output.
Very high efficiency, miniaturized, long-lived alpha particle power source using diamond devices for extreme space environments
The present invention uses the kinetic energy of [alpha]-particles emitted during radioactive decay. Alpha particles are the nuclei of helium atoms that are emitted and travel without the usual accompanying electrons present in un-ionized helium atoms. In comparison to beta particles (electrons) and gamma rays (high energy electromagnetic radiation), [alpha]-particles are massive with kinetic energy that is readily-convertible to electrical energy under the proper circumstances.
With the use of radioactive isotopes, such a power source can be used in environments that are isolated from other power sources.
Solution
- The solution relates to small, high efficiency and long-lived power source.
- The power source includes pn structure in the form of n-doped diamond film and p-doped diamond film.
- The N- and P-doped diamond films are doped at low densities to maximize the depletion region for high efficiency operation.
- Ohmic contacts are used to collect current from the PN junction. Additionally, the entire power generator may be situated atop a diamond substrate.
- Curium 244 is used to provide [alpha]-particles. The kinetic energy of the [alpha]-particles generates free electron and hole pairs.
- [alpha]-particles are massive with kinetic energy that is readily-convertible to electrical energy under the proper circumstances.
Application
- The application of the battery device is spacecraft.
- The application of this could be the environments where human cannot reach, like deep sea and deep space missions.
Comment
- The method is suitable for enhancing the efficiency of the power source.
- The power source includes pn structure in the form of n-doped diamond film and p-doped diamond film.
A safe metal container device equipped with heat dissipation for CVD diamond semiconductor thin film nuclear power cells using radioactive waste.
The present invention relates to a safe metal container device in which radioactive waste is sealed in a metal container and is equipped with a tandem CVD diamond semiconductor thin film ionizing radiation conversion layer heat dissipation layer that converts ionizing radiation emitted from radioactive materials into electric power.
CVD diamond has a band gap of 5.48 eV and has properties as a semiconductor. As the CVD diamond semiconductor thin film, a nanocrystalline diamond thin film formed by high-power microwave plasma CVD, microwave plasma CVD, or surface wave plasma CVD is used.
CVD diamond is said to be a material that has the highest or near-highest values among substances in terms of thermal conductivity, elastic constant, light transmittance, heat resistance, chemical resistance, radiation resistance, insulation, and dielectric breakdown.
Solution
- The solution relates to a safe metal container that converts the ionizing radiation emitted from the radioactive materials into electric power.
- Safe metal container in which radioactive waste is sealed.
- Safe metal container is equipped with a tandem CVD diamond semiconductor thin film ionizing radiation conversion layer and heat dissipation layer.
- A tandem CVD diamond semiconductor thin film ionizing radiation conversion layer that converts X-rays into electricity is used for heat dissipation in a cooling layer using circulating water.
Application
- The method is suitable for utilization of electric power, heat dissipation or shielding of ionizing radiation..
- The heat dissipation of the diamond semiconductor thin film ionizing radiation conversion layer utilizes the power generated by the long-term conversion power generation for more than 100 years.
- The safety of the CVD diamond semiconductor thin film nuclear battery using radioactive waste, which shields ionizing radiation.
Comment
- The solution is suitable for utilization of electric power, heat dissipation or shielding of ionizing radiation.
- The tandem CVD diamond semiconductor thin film ionizing radiation conversion layer installed in a metal container containing radioactive waste converts the ionizing radiation emitted by the radioactive material into electricity.
Nuclear Battery
In the nuclear battery of the present invention, the semiconductor substrate, the metal-doped diamond layer, the active layer, and the radioactive substance-containing layer are laminated in this order, and the electromotive force generated by radiating radiation to the radioactive substance-containing layer has a structure (diode structure) in which an electrode for extracting is electrically connected to these laminates.
A laminate having at least a semiconductor substrate, a metal-doped diamond layer, an active layer, and a radioactive substance-containing layer in this order and an electrode electrically connected to the laminate and the active layer is made of impurity-doped diamond, wherein said metal-doped diamond layer has a metal concentration of 1×10 18 cm −3 or more and 1×10 21 cm −3 or less.
Solution
- The solution relates to a diamond-based nuclear battery.
- A primary object of the solution is to provide a nuclear power battery using diamond, in which degradation of diode characteristics due to an increase in diode area is suppressed.
- By disposing a metal-doped diamond layer between the semiconductor substrate and the active layer, the deterioration of the diode characteristics due to the increase in the area of the diode can be suitably suppressed.
- In nuclear battery of the present invention, the semiconductor substrate, the metal-doped diamond layer, the active layer, and the radioactive substance-containing layer are laminated in this order, and the electromotive force generated by radiating radiation to the radioactive substance-containing layer has a structure (diode structure) in which an electrode for extracting is electrically connected to these laminates.
Application
- The solution is suitable for suppressing the degradation of diode characteristics due to an increase in diode area.
- By disposing a metal-doped diamond layer between the semiconductor substrate and the active layer, the deterioration of the diode characteristics due to the increase in the area of the diode can be suitably suppressed.
Comment
- The method is suitable for suppressing the degradation of diode characteristics due to an increase in diode area.
- A metal-doped diamond layer between the semiconductor substrate and the active layer, the deterioration of the diode characteristics due to the increase in the area of the diode can be suitably suppressed.
A kind of diamond PIM Schottky types β radiation volta effect nuclear battery
The invention provides a diamond PIM Schottky type beta radiation volts effect nuclear battery, which integrates pure beta radioactive source, diamond slowing body and diamond PIM Schottky diode processing into a kind of radioactive source by using a mature preparation process. The device of decay can be converted into electrical energy. This type of nuclear battery is an ideal micro power supply for MEMS due to its high energy conversion efficiency, high radiation resistance, stable output and long service life.
The pure beta radiation source (1) is a flaky cylindrical solid state radiation source. It was selected as a source of lanthanum (Ti3TX), a source of nickel-63 (63Ni), a source of cesium-147 (147Pm2O3) or a source of strontium-90 (90Sr). Further, considering that the beta radiation is derived from the absorption effect, the thickness of the germanium source (Ti3TX) is less than 2 μm; the thickness of the nickel-63 source (63Ni) is less than 3 μm; the thickness of the germanium-147 source (147Pm2O3) is less than 43 μm; the germanium-90 source ( 90Sr) has a thickness of less than 1 cm.
The detachable diamond moderator (2) is cylindrical with a radius equal to the radius of the pure beta source (1). Varying the thickness of the diamond moderator (2) The high energy beta particles emerging from the pure beta source are moderated to obtain lower energy beta particles that are lower than the energy threshold of the diamond PIM Schottky diode for radiation damage and meet the output requirements of the MEMS.
Solution
Application
- The solution is suitable for suppressing the degradation of diode characteristics due to an increase in diode area.
- By disposing a metal-doped diamond layer between the semiconductor substrate and the active layer, the deterioration of the diode characteristics due to the increase in the area of the diode can be suitably suppressed.
Comment
- The method is suitable for suppressing the degradation of diode characteristics due to an increase in diode area.
- A metal-doped diamond layer between the semiconductor substrate and the active layer, the deterioration of the diode characteristics due to the increase in the area of the diode can be suitably suppressed.
A kind of diamond PIM Schottky types β radiation volta effect nuclear battery
The invention provides a diamond PIM Schottky type beta radiation volts effect nuclear battery, which integrates pure beta radioactive source, diamond slowing body and diamond PIM Schottky diode processing into a kind of radioactive source by using a mature preparation process. The device of decay can be converted into electrical energy. This type of nuclear battery is an ideal micro power supply for MEMS due to its high energy conversion efficiency, high radiation resistance, stable output and long service life.
The pure beta radiation source (1) is a flaky cylindrical solid state radiation source. It was selected as a source of lanthanum (Ti3TX), a source of nickel-63 (63Ni), a source of cesium-147 (147Pm2O3) or a source of strontium-90 (90Sr). Further, considering that the beta radiation is derived from the absorption effect, the thickness of the germanium source (Ti3TX) is less than 2 μm; the thickness of the nickel-63 source (63Ni) is less than 3 μm; the thickness of the germanium-147 source (147Pm2O3) is less than 43 μm; the germanium-90 source ( 90Sr) has a thickness of less than 1 cm.
The detachable diamond moderator (2) is cylindrical with a radius equal to the radius of the pure beta source (1). Varying the thickness of the diamond moderator (2) The high energy beta particles emerging from the pure beta source are moderated to obtain lower energy beta particles that are lower than the energy threshold of the diamond PIM Schottky diode for radiation damage and meet the output requirements of the MEMS.
Solution
- The solution relates to a battery device for converting a decay energy of a radionuclide into electric energy by using a semiconductor device, and belongs to the technical field of nuclear energy utilization.
- A diamond PIM Schottky type beta radiation volts effect nuclear battery, which integrates pure beta radioactive source, diamond slowing body and diamond PIM Schottky diode processing into a kind of radioactive source by using a mature preparation process.
- The use of semiconductor devices can convert the decay of radionuclide to the cell apparatus of electric energy, belong to Nuclear energy utilization technology field.
- This type of nuclear battery is an ideal micro power supply for MEMS due to its high energy conversion efficiency, high radiation resistance, stable output and long service life.
Application
The solution improves an ideal micro power supply for MEMS due to its high energy conversion efficiency, high radiation resistance, stable output and long service life.
Comment
- The solution is suitable for converting a decay energy of a radionuclide into electric energy by using a semiconductor device.
- PM-type diamond Schottky barrier, reduce the leakage current of the diamond Schottky diode, and increase the open circuit voltage of the nuclear battery and energy conversion efficiency.
Energy loading and transduction integrated nuclear battery
The purpose of the present invention is to reduce the influence of radiation originating from the absorption effect, improve the electrical performance of the radiation volt-effect nuclear battery, and at the same time reduce the impact of radiation damage on the electrical performance of the nuclear battery.
The pn junction nuclear battery, the radioactive source, the positive electrode, the semiconductor transducer, and the back electrode are respectively from top to bottom. Due to the self-absorption effect of the radioactive source, only part of the alpha or beta particles produced by its decay can be emitted, and only part of the decay energy of the radioactive source can be used.
Solution
- The solution relates to reduce the influence of radiation originating from the absorption effect, improve the electrical performance of the radiation volt-effect nuclear battery, and at the same time reduce the impact of radiation damage on the electrical performance of the nuclear battery.
- The energy-carrying and energy-conversion integrated nuclear battery contains 1-highly doped semiconductor substrate with radioactivity, 2 -Low-doped radioactive semiconductor layer, 3-battery Schottky metal layer, 4-battery ohmic electrode, 5-sealed casing.
- The 1-highly doped radioactive semiconductor substrate and the 2-lowly doped radioactive semiconductor layer may be a semiconductor material that itself contains radioactivity, preferably diamond, Si14C composed of a carbon isotope 14C with beta radioactivity Or 63NiO and other wide-gap semiconductor materials composed of beta-radioactive nickel isotopes.
Application
The nuclear battery can be applied to severe environments and occasions where human beings are difficult to reach for a long time, such as deep sea, deep space, polar regions, remote areas and cardiac pacemakers.
Comment
- The solution relates to reduce the impact of radiation damage on the electrical performance of the nuclear battery.
- The invention combines the radioactive source and the semiconductor into a whole, avoids energy loss caused by deposition of the radioactive source in the Schottky metal, and further improves the energy utilization rate of the radioactive source.
Diamond Schottky type beta radiation volt effect miniature nuclear battery
The invention provides a miniature nuclear battery based on diamond Schottky type beta radiation volt effect, which utilizes a mature preparation process to process and integrate a pure beta radiation source, a diamond moderator and a diamond Schottky diode into a radioactive source. A device that converts decay energy into electrical energy. This type of nuclear battery is an ideal micro power source for MEMS due to its high energy conversion efficiency, strong radiation resistance, stable output and long service life.
A diamond Schottky type beta radiation volt effect miniature nuclear battery. The pure beta radiation source is a flake-shaped cylindrical solid-state radiation source. Selected as tritium source (3HXTi), nickel-63 source (63Ni), promethium-147 source (147Pm2O3) and strontium/yttrium-90 source (90Sr/90Y). Further, considering that the β radiation originates from the absorption effect, the thickness of the tritium source (3HXTi) is less than 2 μm; the thickness of the nickel-63 source (63Ni) is less than 3 μm; the thickness of the promethium-147 source (147Pm2O3) is less than 43 μm; strontium/yttrium-90 The thickness of the source (90Sr/90Y) is less than 1 cm.
Solution
- The solution relates to a battery device that utilizes semiconductor devices to convert the decay energy of radionuclides into electrical energy.
- A miniature nuclear battery based on diamond Schottky type beta radiation volt effect, which utilizes a mature preparation process to process and integrate a pure beta radiation source, a diamond moderator and a diamond Schottky diode into a radioactive source.
- The diamond Schottky diode is cylindrical, the radius of which is the same as that of the pure beta radiation source, and the interior of the diode is sequentially stacked with a P-type high-doped diamond substrate layer and a P-type low-doped diamond buffer layer. layer, intrinsic diamond layer and Schottky electrode layer.
Application
Comment
- The solution relates to a battery device that utilizes semiconductor devices to convert the decay energy of radionuclides into electrical energy.
- The solution improves the energy conversion efficiency and energy output power of the nuclear battery, and at the same time prolongs the service life of the nuclear battery, and the performance of the nuclear battery is stable.
Solid State Electric Generator Using Radionuclide-induced Exciton Production
The nuclear particles interact with the crystal atom electrons- by a variety of mechanisms and generate a bound electron-hole pair that, when recombination occurs, yields a photon. An important photon production mechanism is the EXCITON mechanism, but by recombination in direct band gap materials, color centers, defects and vacancy mechanisms also play an important role. The photon that results from the electron-hole recombination or fluorescence may be converted to electrical energy.
The present invention also concerns the method of producing a DEXRG device, which includes the step of manufacturing diamond film by means of chemical vapor deposition (CVD) techniques. Then, the diamond film is processed, preferably by means of a forced diffusion process, to impregnate radioactive isotopes such as tritium or krypton- 85 into the diamond interstitial voids and crystal boundaries.
The device is sealed in a manner that will prevent radioactive leakage but to permit access to the generated electrical energy.
Solution
The nuclear particles interact with the crystal atom electrons- by a variety of mechanisms and generate a bound electron-hole pair that, when recombination occurs, yields a photon. An important photon production mechanism is the EXCITON mechanism, but by recombination in direct band gap materials, color centers, defects and vacancy mechanisms also play an important role. The photon that results from the electron-hole recombination or fluorescence may be converted to electrical energy.
The present invention also concerns the method of producing a DEXRG device, which includes the step of manufacturing diamond film by means of chemical vapor deposition (CVD) techniques. Then, the diamond film is processed, preferably by means of a forced diffusion process, to impregnate radioactive isotopes such as tritium or krypton- 85 into the diamond interstitial voids and crystal boundaries.
The device is sealed in a manner that will prevent radioactive leakage but to permit access to the generated electrical energy.
Solution
- The solution provides an apparatus for providing electric and thermal power by employing several physical characteristics of thin crystalline films or plates made from wide band-gap materials, including the ability of such materials to store an isotope that emits decay energy.
- Beta or alpha particles may provide the primary energy source.
- The present invention concerns the combination of diamond as a storage medium and a radioactive isotope, which is impregnated into the diamond crystalline structure so that the interstitial voids between the carbon atoms of the diamond structure are each occupied by an atom of the radioactive isotope.
- The invention relies upon the use of any one of a number of luminescent mechanisms by which crystal lattices produce electromagnetic radiation in response to charged particle irradiation, e.g., the EXCITON mechanism or emission due to color centers, defects or vacancies effect to provide a conversion of the emitted particles to photons, which subsequently are converted to electrical energy.
Application
- The solution permit the use of the power source in a wide variety of spacecraft and planetary surface systems.
- The solution have other applications like spacecraft, aircraft, submersible vehicles, surface vehicles or static equipment.
Comment
- The solution provides an apparatus for providing electric and thermal power.
- The method of producing a DEXRG device, which includes the step of manufacturing diamond film by means of chemical vapor deposition (CVD) techniques.
Process For Integrating Tritium Into Diamond
The present inventors have found that tritium can be integrated into diamond, i.e. a diamond semiconductor, after the diamond (e.g. synthetic diamond) has been formed. The present inventors have found that tritium can be infused or implanted into diamond to provide diamond containing tritium, wherein tritium is substitutionally and/or interstitially integrated into the diamond.
A Diamond Schottky Diode, with Tritium as the active energy source, each beta decay provides an e„ of approximately 360 electrons, this invention provides for maximal device efficiency in that these electrons elevated to the conduction band are in the drift region of the semiconductor for maximum collection and providing increased power generation and efficiency.
In place of tritium, deuterium can be employed in the processes described herein to produce diamond containing deuterium.
Solution
- The solution relates to infusion of tritium into diamond to provide better efficiency.
- Tritium (hydrogen-3) is a radioactive isotope of hydrogen which is a pure beta emitter and have low mass, a compatible energy spectrum of the emitted beta particles on decay with an average energy of 5.6keV, and being readily available as a waste product from the nuclear industry.
- Semiconductor depletion area is where electrical charge exists, this in-built device voltage or potential gradient provides a drift zone for the movement and efficient collection of electrons.
- Beta-voltaic devices, e.g. devices having improved efficiency, due to providing for an atomic- level integration of the beta radioisotope directly into the diamond.
Application
Comment
- The solution relates to infusion of tritium into diamond to provide better efficiency.
- In place of tritium, deuterium can be employed in the processes described herein to produce diamond containing deuterium.
Radiation powered devices comprising diamond material and electrical power sources for radiation powered devices
The present inventors have identified that diamond is in many ways the ideal material for use in radiation powered devices such as radioisotope batteries and related devices. First, diamond is extremely radiation hard and therefore has a higher tolerance, to ionising radiation than other semiconductor materials improving stability and lifetime.
In certain embodiments the diamond material in which a radioactive source is embedded is a synthetic diamond material in which the radioactive source (e.g. radioisotope atoms) is integrated during formation of the diamond material. For example, tritium and/or 14 C may be integrated into the diamond crystal lattice during formation of the diamond material.
Solution
- The solution relates to radiation powered devices comprising diamond material, and electrical power sources for radiation powered devices.
- A radiation powered device is provided which comprises: a first electrode; a second electrode; a semiconductor disposed between the first and second electrodes; and a radioactive source configured to generate a flow of electrons through the semiconductor between the first and second electrodes; wherein the semiconductor comprises diamond material; and wherein the radioactive source is embedded within the diamond material.
- The radioactive source may be embedded within the diamond material such that, for example, atoms of a radioisotope of the radioactive source are either substitutionally or interstitially integrated into the diamond material, that is substitutionally or interstitially integrated into the crystal lattice of the diamond material, to form a constituent part of the diamond material.
Application
Comment
- The solution relates to radiation powered devices comprising diamond material, and electrical power sources for radiation powered devices.
- The diamond material in which a radioactive source is embedded is a synthetic diamond material in which the radioactive source (e.g. radioisotope atoms) is integrated during formation of the diamond material.
Read Part 1: Nano Diamond Batteries – Overview and Key Players
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